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. 2010 Aug 7;8(15):3402-4.
doi: 10.1039/c0ob00170h. Epub 2010 Jun 25.

Ultrafast Grignard addition reactions in the presence of water

Gyorgyi Osztrovszky  1 , Torkil Holm, Robert Madsen
Affiliations

Ultrafast Grignard addition reactions in the presence of water

Gyorgyi Osztrovszky et al. Org Biomol Chem. .

Abstract

The addition of allylmagnesium bromide and benzylmagnesium chloride to carbonyl compounds was investigated in the presence of protic reagents such as water and the rate of carbonyl addition was found to be comparable to the rate of protonation by the reagent.

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