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. 2010 Aug 6;12(15):3564-6.
doi: 10.1021/ol101435w.

Stabilized alpha-helix-catalyzed enantioselective epoxidation of alpha,beta-unsaturated ketones

Masanobu Nagano  1 , Mitsunobu Doi, Masaaki Kurihara, Hiroshi Suemune, Masakazu Tanaka
Affiliations

Stabilized alpha-helix-catalyzed enantioselective epoxidation of alpha,beta-unsaturated ketones

Masanobu Nagano et al. Org Lett. .

Abstract

Chiral cyclic alpha-amino acid containing oligopeptide catalyzed highly enantioselective epoxidation of alpha,beta-unsaturated ketones and the alpha-helical secondary structure of the peptide catalyst were revealed by X-ray crystallographic analysis.

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