Review
doi: 10.3109/10715769109145820.
Studies of hypervalent iron
Affiliations
- PMID: 2060824
- DOI: 10.3109/10715769109145820
Item in Clipboard
Review
Studies of hypervalent iron
Free Radic Res Commun.
1991.
Abstract
The iron(IV), (V) and (VI) oxidation states are of great interest because of their role in catalytic oxidation/hydroxylation reactions. This report summarizes the information currently available on the kinetic and chemical properties of the water-soluble ions of FeO4(2-), FeO4(3-), and FeO4(4-), their protonated forms and/or simple complex derivatives. The discussion includes their radiation-induced formation, decay kinetics, reactivity with other compounds, determination of their respective pKa values as well as spectral properties.
Similar articles
-
Reactivity of hypervalent iron with biological compounds.Ann Neurol. 1992;32 Suppl:S28-32. doi: 10.1002/ana.410320707. Ann Neurol. 1992. PMID: 1510378 Review.
-
The reduction of ferrate(VI) to ferrate(V) by ascorbate.Free Radic Biol Med. 1991;11(2):157-60. doi: 10.1016/0891-5849(91)90166-z. Free Radic Biol Med. 1991. PMID: 1937133
-
Kinetic simulation studies on the transient formation of the oxo-iron(IV) porphyrin radical cation during the reaction of iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)-porphyrin with hydrogen peroxide in aqueous solution.Luminescence. 2003 Sep-Oct;18(5):259-67. doi: 10.1002/bio.736. Luminescence. 2003. PMID: 14587077
-
Tuning reactivity and mechanism in oxidation reactions by mononuclear nonheme iron(IV)-oxo complexes.Acc Chem Res. 2014 Apr 15;47(4):1146-54. doi: 10.1021/ar400258p. Epub 2014 Feb 13. Acc Chem Res. 2014. PMID: 24524675
-
Review of kinetics of chemical and photocatalytical oxidation of Arsenic(III) as influenced by pH.J Environ Sci Health A Tox Hazard Subst Environ Eng. 2007 Jun;42(7):997-1004. doi: 10.1080/10934520701373034. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2007. PMID: 17558780 Review.
Cited by
-
Metals and lipid oxidation. Contemporary issues.Lipids. 1992 Mar;27(3):209-18. doi: 10.1007/BF02536181. Lipids. 1992. PMID: 1522766 Review.
-
Ferrate (VI), Fenton Reaction and Its Modification: An Effective Method of Removing SARS-CoV-2 RNA from Hospital Wastewater.Pathogens. 2022 Apr 9;11(4):450. doi: 10.3390/pathogens11040450. Pathogens. 2022. PMID: 35456125 Free PMC article.
-
On the Origins of Some Spectroscopic Properties of "Purple Iron" (the Tetraoxoferrate(VI) Ion) and Its Pourbaix Safe-Space.Molecules. 2021 Aug 30;26(17):5266. doi: 10.3390/molecules26175266. Molecules. 2021. PMID: 34500697 Free PMC article. Review.
-
Potassium ferrate [Fe(VI)] does not mediate self-sterilization of a surrogate Mars soil.BMC Microbiol. 2003 Mar 6;3:4. doi: 10.1186/1471-2180-3-4. Epub 2003 Mar 6. BMC Microbiol. 2003. PMID: 12694634 Free PMC article.
Publication types
MeSH terms
Substances
LinkOut - more resources
Medical