Self-assembled cage as an endo-template for cyclophane synthesis
- PMID: 20614091
- DOI: 10.1039/c0cc00963f
Self-assembled cage as an endo-template for cyclophane synthesis
Abstract
An organic-pillared coordination cage templated the quantitative formation of siloxane-bridged cyclophanes within its cavity via hydrolysis and condensation of 1,6- and 1,8-bis(trimethoxysilyl)pyrene.
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