Review
doi: 10.1039/b915662c.
Epub 2010 Aug 4.
Stereospecific and highly stereoselective cyclopropanation reactions promoted by samarium
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- PMID: 20683534
- DOI: 10.1039/b915662c
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Review
Stereospecific and highly stereoselective cyclopropanation reactions promoted by samarium
Chem Soc Rev.
2010 Nov.
Abstract
Samarium metal and samarium diiodide have become important tools as selective cyclopropanating agents in organic synthesis due to their high chemo- and stereoselectivity. Therefore, Sm and SmI(2) are the ideal reagents to prepare cyclopropane derivatives. This tutorial review highlights C-C multiple bond cyclopropanation processes promoted by samarium or samarium diiodide.
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