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. 2010 Sep 1;132(34):11900-1.
doi: 10.1021/ja105124r.

Spin and orbital magnetic moment anisotropies of monodispersed bis(phthalocyaninato)terbium on a copper surface

Sebastian Stepanow  1 , Jan Honolka, Pietro Gambardella, Lucia Vitali, Nasiba Abdurakhmanova, Tzu-Chun Tseng, Stephan Rauschenbach, Steven L Tait, Violetta Sessi, Svetlana Klyatskaya, Mario Ruben, Klaus Kern
Affiliations

Spin and orbital magnetic moment anisotropies of monodispersed bis(phthalocyaninato)terbium on a copper surface

Sebastian Stepanow et al. J Am Chem Soc. .

Abstract

The magnetic properties of isolated TbPc(2) molecules supported on a Cu(100) surface are investigated by X-ray magnetic circular dichroism at 8 K in magnetic fields up to 5 T. The crystal field and magnetic properties of single molecules are found to be robust upon adsorption on a metal substrate. The Tb magnetic moment has Ising-like magnetization; XMCD spectra combined with multiplet calculations show that the saturation orbital and spin magnetic moment values reach 3 and 6 mu(B), respectively.

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