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. 2010 Sep 1;132(34):11847-9.
doi: 10.1021/ja103786c.

Enantioselective organocatalytic C-H bond functionalization via tandem 1,5-hydride transfer/ring closure: asymmetric synthesis of tetrahydroquinolines

Young Ku Kang  1 , Sun Mi Kim, Dae Young Kim
Affiliations

Enantioselective organocatalytic C-H bond functionalization via tandem 1,5-hydride transfer/ring closure: asymmetric synthesis of tetrahydroquinolines

Young Ku Kang et al. J Am Chem Soc. .

Abstract

The first organocatalytic enantioselective intramolecular 1,5-hydride transfer/ring closure reaction is described. This redox neutral reaction cascade allows for the efficient formation of ring-fused tetrahydroquinolines in high enantioselectivities.

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