doi: 10.1021/ja1058247.
Cp* iridium complexes give catalytic alkane hydroxylation with retention of stereochemistry
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- PMID: 20731395
- DOI: 10.1021/ja1058247
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Cp* iridium complexes give catalytic alkane hydroxylation with retention of stereochemistry
J Am Chem Soc.
.
Abstract
A series of Cp*Ir complexes can catalyze C-H oxidation, with ceric ammonium nitrate as the terminal oxidant and water as the source of oxygen. Remarkably the hydroxylation of cis-decalin and 1,4-dimethylcyclohexane proceeds with retention of stereochemistry. With H(2)O(18), cis-decalin oxidation gave (18)O incorporation into the product cis-decalol.
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