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. 2010 Oct 7;46(37):6932-4.
doi: 10.1039/c0cc01039a. Epub 2010 Aug 23.

Exopericyclic stereocontrol in Johnson-Claisen rearrangements of allylic sulfides

Donald Craig  1 , John W Harvey, Alexander G O'Brien, Andrew J P White
Affiliations

Exopericyclic stereocontrol in Johnson-Claisen rearrangements of allylic sulfides

Donald Craig et al. Chem Commun (Camb). .

Abstract

A study of the effects of exopericyclic stereocentres on the stereoselectivity of Johnson-Claisen rearrangements of thioether-containing allylic alcohols shows that selectivity is highly dependent upon allylic substitution patterns.

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