Copper-catalyzed olefin aminoacetoxylation
- PMID: 20735066
- DOI: 10.1021/ol101702w
Copper-catalyzed olefin aminoacetoxylation
Abstract
A new catalyst system for intramolecular olefin aminoacetoxylation is described. In contrast to previously reported palladium- and copper-catalyzed systems, the conditions outlined in this communication favor piperdine formation with terminal olefin substrates and induce cyclization with traditionally less reactive disubstituted olefins.
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