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. 2010 Sep 6;49(17):7605-7.
doi: 10.1021/ic100822s.

Control over interpenetration in lanthanide-organic frameworks: synthetic strategy and gas-adsorption properties

Haiyan He  1 , Daqiang Yuan, Huiqing Ma, Daofeng Sun, Guoqing Zhang, Hong-Cai Zhou
Affiliations

Control over interpenetration in lanthanide-organic frameworks: synthetic strategy and gas-adsorption properties

Haiyan He et al. Inorg Chem. .

Abstract

Two isostructural lanthanide-organic frameworks (1 and 2) with 2-fold interpenetrating nets have been synthesized based on 1,4-benzenedicarboxylic acid (H(2)BDC). By application of an organic ligand with hindrance groups and a terminal chelating ligand to replace BDC and coordinated solvates, interpenetration has been effectively controlled. The gas-sorption properties of the noninterpenetrating net have been studied.

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