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. 2010 Oct 15;12(20):4454-7.
doi: 10.1021/ol101915b.

Regio- and enantioselective iridium-catalyzed allylation of thiophenol: synthesis of enantiopure allyl phenyl sulfides

Shengcai Zheng  1 , Ning Gao, Wei Liu, Dongge Liu, Xiaoming Zhao, Theodore Cohen
Affiliations

Regio- and enantioselective iridium-catalyzed allylation of thiophenol: synthesis of enantiopure allyl phenyl sulfides

Shengcai Zheng et al. Org Lett. .

Abstract

A highly regio- and enantioselective allylic alkylation of sodium thiophenoxide has been realized by [Ir(COD)Cl](2)/phosphoramidite along with CsF as an additive, producing highly enantioenriched allyl phenyl sulfide compounds with up to 99% ee.

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