Enantioselective rhodium-catalyzed addition of arylboronic acids to alkenylheteroarenes
- PMID: 20879736
- DOI: 10.1021/ja106809p
Enantioselective rhodium-catalyzed addition of arylboronic acids to alkenylheteroarenes
Abstract
In the presence of a rhodium complex containing a newly developed chiral diene ligand, alkenes activated by a range of π-deficient or π-excessive heteroarenes engage in highly enantioselective conjugate additions with various arylboronic acids.
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