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. 2010 Oct 20;132(41):14373-5.
doi: 10.1021/ja106809p.

Enantioselective rhodium-catalyzed addition of arylboronic acids to alkenylheteroarenes

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Enantioselective rhodium-catalyzed addition of arylboronic acids to alkenylheteroarenes

Graham Pattison et al. J Am Chem Soc. .

Abstract

In the presence of a rhodium complex containing a newly developed chiral diene ligand, alkenes activated by a range of π-deficient or π-excessive heteroarenes engage in highly enantioselective conjugate additions with various arylboronic acids.

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