Sensitive surface loop-gap microresonators for electron spin resonance
- PMID: 21034106
- DOI: 10.1063/1.3488365
Sensitive surface loop-gap microresonators for electron spin resonance
Abstract
This work presents the design, construction, and experimental testing of unique sensitive surface loop-gap microresonators for electron spin resonance (ESR) measurements. These resonators are made of "U"-shaped gold structures with typical sizes of 50 and 150 μm that are deposited on a thin (220 μm) rutile substrate and fed from the rear by a microstrip line. This allows accommodating a large flat sample above the resonator in addition to having variable coupling properties. Such resonators have a very small volume which, compared to previous designs, improves their absolute spin sensitivity by a factor of more than 2 (based on experimental results). They also have a very high microwave field-power conversion ratio of up to 86 gauss/√Hz. This could facilitate the use of very short excitation pulses with relatively low microwave power. Following the presentation and the discussion of the experimental results, ways to further increase sensitivity significantly are outlined.
Similar articles
-
Rutile dielectric loop-gap resonator for X-band EPR spectroscopy of small aqueous samples.J Magn Reson. 2019 Oct;307:106585. doi: 10.1016/j.jmr.2019.106585. Epub 2019 Aug 28. J Magn Reson. 2019. PMID: 31499469 Free PMC article.
-
Uniform field loop-gap resonator and rectangular TEU02 for aqueous sample EPR at 94GHz.J Magn Reson. 2017 Sep;282:129-135. doi: 10.1016/j.jmr.2017.08.001. Epub 2017 Aug 5. J Magn Reson. 2017. PMID: 28803092 Free PMC article.
-
Cryogenic Q-band (35GHz) probehead featuring large excitation microwave fields for pulse and continuous wave electron paramagnetic resonance spectroscopy: performance and applications.J Magn Reson. 2008 Feb;190(2):280-91. doi: 10.1016/j.jmr.2007.11.009. Epub 2007 Nov 17. J Magn Reson. 2008. PMID: 18055237
-
Uniform Field Resonators for EPR Spectroscopy: A Review.Cell Biochem Biophys. 2019 Mar;77(1):3-14. doi: 10.1007/s12013-018-0845-6. Epub 2018 Jun 25. Cell Biochem Biophys. 2019. PMID: 29943362 Free PMC article. Review.
-
Detection of bioradicals by in vivo L-band electron spin resonance spectrometry.NMR Biomed. 2004 Aug;17(5):311-8. doi: 10.1002/nbm.898. NMR Biomed. 2004. PMID: 15366030 Review.
Cited by
-
Recent advances in microresonators and supporting instrumentation for electron paramagnetic resonance spectroscopy.Rev Sci Instrum. 2022 Oct 1;93(10):101101. doi: 10.1063/5.0097853. Rev Sci Instrum. 2022. PMID: 36319314 Free PMC article.
-
Continuous-flow electron spin resonance microfluidics device with sub-nanoliter sample volume.J Magn Reson Open. 2025 Sep;24:100207. doi: 10.1016/j.jmro.2025.100207. Epub 2025 Jul 9. J Magn Reson Open. 2025. PMID: 40832003 Free PMC article.
-
Extending electron paramagnetic resonance to nanoliter volume protein single crystals using a self-resonant microhelix.Sci Adv. 2019 Oct 4;5(10):eaay1394. doi: 10.1126/sciadv.aay1394. eCollection 2019 Oct. Sci Adv. 2019. PMID: 31620561 Free PMC article.
-
Celebration of 80 years of EPR.Appl Magn Reson. 2024 Sep;55(9):869-888. doi: 10.1007/s00723-024-01688-2. Epub 2024 Jul 24. Appl Magn Reson. 2024. PMID: 40191657 Free PMC article.
Publication types
MeSH terms
Substances
Grants and funding
LinkOut - more resources
Full Text Sources
Other Literature Sources
Miscellaneous