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. 2011 Feb 28;47(8):2354-6.
doi: 10.1039/c0cc03844j. Epub 2010 Dec 13.

Gold-complexes catalyzed oxidative α-cyanation of tertiary amines

Yan Zhang  1 , Hao Peng, Ming Zhang, Yixiang Cheng, Chengjian Zhu
Affiliations

Gold-complexes catalyzed oxidative α-cyanation of tertiary amines

Yan Zhang et al. Chem Commun (Camb). .

Abstract

Oxidative α-cyanation of tertiary amines is catalyzed by gold complexes with trimethylsilyl cyanide to afford the corresponding α-aminonitriles in the presence of tert-butyl hydroperoxide in good to excellent yields under acid-free conditions at room temperature.

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