Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2007 Dec 6;64(Pt 1):m129-30.
doi: 10.1107/S1600536807065208.

(μ-4-Bromo-2-{1-[2-(dimethyl-amino)ethyl-imino]eth-yl}phenolato)bis-[ethyl-zinc(II)]

(μ-4-Bromo-2-{1-[2-(dimethyl-amino)ethyl-imino]eth-yl}phenolato)bis-[ethyl-zinc(II)]

Wen-Chou Hung et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title complex, [Zn(2)(C(2)H(5))(2)(C(12)H(16)BrN(2)O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The molecule lies on a crystallographic twofold rotation axis. Each Zn atom is penta-coordinated by two N atoms and two bridging O atoms of the tridentate salicylideneiminate ligands and one C atom from an ethyl group, forming a distorted square-pyramidal environment.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
A view of the molecular structure of (I) with displacement ellipsoids shown at the 20% probability level.

References

    1. Bruker (1999). SMART, SAINT and SHELXTL Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Chamberlain, B. M., Cheng, M., Moore, D. R., Ovitt, T. M., Lobkovsky, E. B. & Coates, G. W. (2001). J. Am. Chem. Soc 123, 3229–3238. - PubMed
    1. Chen, H. Y., Huang, B. H. & Lin, C. C. (2005). Macromolecules, 38, 5400–5405.
    1. Chen, H. Y., Tang, H. Y. & Lin, C. C. (2006). Macromolecules, 39, 3745–5752.
    1. Chisholm, M. H., Eilerts, N. W., Huffman, J. C., Iyer, S. S., Pacold, M. & Phomphrai, K. (2000). J. Am. Chem. Soc.122, 11845–11854.

LinkOut - more resources