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. 2008 Sep 20;64(Pt 10):m1304.
doi: 10.1107/S1600536808029814.

{2,6-Bis[(di-tert-butyl-phosphino)-methyl]-phenyl}chloridonickel(II)

Brian J Boro, Diane A Dickie, Karen I Goldberg, Richard A Kemp

{2,6-Bis[(di-tert-butyl-phosphino)-methyl]-phenyl}chloridonickel(II)

Brian J Boro et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Ni(C(24)H(43)P(2))Cl], the Ni atom adopts a distorted square-planar geometry, with the P atoms of the 2,6-bis-[(di-tert-butyl-phosphino)meth-yl]phenyl ligand trans to one another. The P-Ni-P plane is twisted out of the plane of the aromatic ring by 21.97 (6)°.

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Figures

Fig. 1.
Fig. 1.
View of the title compound showing numbering scheme. Ellipsoids are shown at 50% probability and hydrogen atoms have been removed for clarity.
See this image and copyright information in PMC

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