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. 2008 Sep 13;64(Pt 10):o1930.
doi: 10.1107/S1600536808028730.

1,4-Dibromo-2,5-bis-(hex-yloxy)benzene

1,4-Dibromo-2,5-bis-(hex-yloxy)benzene

Ying-Fei Li et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the centrosymmetric title compound, C(18)H(28)Br(2)O(2), the alkyl chains adopt a fully extended all-trans conformation and each of them is almost planar. In addition, the alkyl chains are coplanar with the benzene ring. Inter-molecular Br⋯Br inter-actions [3.410 (3) Å] are present, resulting in a one-dimensional supra-molecular architecture.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound with displacement ellipsoids at the 50% probability level. Inversion related atoms are labelled with an A. (Symmetry code: -x, 1 - y, -z).
Fig. 2.
Fig. 2.
Partial view of the crystal packing showing the formation of the infinite chains of molecules formed by the intermolecular Br···Br interactions. Intercalated neighboring chains complete the sheets in the structure running parallel to (100). H atoms have been omitted for clarity.

References

    1. Ali, B. F., Al-Far, R. H. & Haddad, S. F. (2008). Acta Cryst. E64, m751–m752. - PMC - PubMed
    1. Brammer, L. (2004). Chem. Soc. Rev.33, 476–489. - PubMed
    1. Bruker (2004). SMART and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Desiraju, G. R. & Parthasarathy, R. (1989). J. Am. Chem. Soc.111, 8725–8726.
    1. Kuriger, T. M., Moratti, S. C. & Simpson, J. (2008). Acta Cryst. E64, o709. - PMC - PubMed