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. 2008 Sep 20;64(Pt 10):o1976.
doi: 10.1107/S1600536808029899.

4-Chloro-N-(3-methoxy-phen-yl)-benz-amide

Aamer Saeed, Rasheed Ahmad Khera, Naeem Abbas, Jim Simpson, Roderick G Stanley

4-Chloro-N-(3-methoxy-phen-yl)-benz-amide

Aamer Saeed et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title benzamide derivative, C(14)H(12)ClNO(2), crystallizes with two independent mol-ecules in the asymmetric unit. Both are close to being planar, with dihedral angles between the two benzene rings of 11.92 (6) and 12.80 (7)°. In the crystal structure, N-H⋯O hydrogen bonds link mol-ecules into chains along a. These inter-actions are augmented by C-H⋯O hydrogen bonds to form two-dimensional layers in the ac plane. Additional C-H⋯O inter-actions result in a three-dimensional network consisting of undulating rows along c. The crystal studied was an inversion twin with a 0.59 (3):0.41 (3) domain ratio.

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Figures

Fig. 1.
Fig. 1.
The asymmetric unit of (I) with displacement ellipsoids for the non-hydrogen atoms drawn at the 50% probability level.
Fig. 2.
Fig. 2.
The two dimensional network in (I) formed by N—H···O and C—H···O interactions.
Fig. 3.
Fig. 3.
Crystal packing of (I) viewed down the a axis.
See this image and copyright information in PMC

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