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. 2008 Jan 9;64(Pt 2):m307.
doi: 10.1107/S1600536808000226.

Bis{μ-2,2'-[1,1'-(ethane-1,2-diyldinitrilo)diethyl-idyne]diphenolato-κO,N,N',O':O}bis-[chloridomanganese(III)]

V S Thampidas, T Radhakrishnan, Robert D Pike

Bis{μ-2,2'-[1,1'-(ethane-1,2-diyldinitrilo)diethyl-idyne]diphenolato-κO,N,N',O':O}bis-[chloridomanganese(III)]

V S Thampidas et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, [Mn(2)(C(18)H(18)N(2)O(2))(2)Cl(2)], was synthesized by the reaction between manganese(II) o-chloro-benzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxy-acetophenone. The centrosymmetric dimer contains two Jahn-Teller-distorted mangan-ese(III) ions, each in an octa-hedral geometry, connected through two phen-oxy bridges from two ligands.

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Figures

Fig. 1.
Fig. 1.
Molecular structure of the title compound. Displacement ellipsoids are drawn at the 50% probability level. [Symmetry code: (i) -x, 2 - y, -z.]
See this image and copyright information in PMC

References

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