Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2008 Jan 18;64(Pt 2):m371-2.
doi: 10.1107/S1600536807060734.

(Acetyl-acetonato-κO,O')-aqua-[salicyl-aldehyde nicotinoylhydrazonato(2-)-κO,N,O']manganese(III)

Zeng-You Wang  1 , Shi-Xiong Liu, Zhong-Wu Fu
Affiliations

(Acetyl-acetonato-κO,O')-aqua-[salicyl-aldehyde nicotinoylhydrazonato(2-)-κO,N,O']manganese(III)

Zeng-You Wang et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The Mn(III) atom in the title complex, [Mn(C(13)H(9)N(3)O(2))(C(5)H(7)O(2))(H(2)O)], is coordinated by three donors from a dianionic ligand, salicylaldehyde nicotylhydrazone, two O atoms from an acetyl-acetonate anion and a water mol-ecule in a distorted octa-hedral geometry. There is an extended two-dimensional supra-molecular motif resulting from O-H⋯N hydrogen bonds between the coordinated water mol-ecule and a hydrazine N or pyridine N atom, and from C-H⋯O hydrogen bonds between a CH group and the phenolate O atom.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
The molecular structure of (I), with the atom-numbering scheme and 30% probability displacement ellipsoids.
Fig. 2.
Fig. 2.
A plot illustrating extended two-dimensional structure of (I), hydrogen bonds are drawn as dashed lines. H atoms not-involved in hydrogen bonding have been omitted.
Fig. 3.
Fig. 3.
The extended two-dimensional net-work connected by hydrogen bonds, which are drawn as dashed lines. H atoms not-involved in hydrogen bonding have been omitted.
See this image and copyright information in PMC

References

    1. Adams, H., Fenton, D. E., Minardi, G., Mura, E., Pistuddi, A. M. & Solinas, C. (2000). Inorg. Chem. Commun.3, 24–28.
    1. Batten, S. R. & Robson, R. (1998). Angew. Chem. Int. Ed.37, 1460–1494. - PubMed
    1. Clérac, R., Miyasaka, H., Yamashita, M. & Coulon, C. (2002). J. Am. Chem. Soc.124, 12837–12844. - PubMed
    1. Graham, P. M. & Pike, R. D. (2000). Inorg. Chem.39, 5121–5132. - PubMed
    1. Hagrman, P. J., Hagrman, D. & Zubieta, J. (1999). Angew. Chem. Int. Ed.38, 2638–2684. - PubMed