Bis(3-bromo-methyl-2-meth-oxy-1-naphth-yl)methane
- PMID: 21201830
- PMCID: PMC2960732
- DOI: 10.1107/S1600536808027529
Bis(3-bromo-methyl-2-meth-oxy-1-naphth-yl)methane
Abstract
The title compound, C(25)H(22)Br(2)O(2), crystallizes with two mol-ecules in the asymmetric unit. In each independent mol-ecule, the two naphthalene ring systems are nearly perpendicular to one another, with dihedral angles of 85.6 (1) and 86.2 (1)°. The crystal structure is stabilized by C-H⋯π inter-actions, and inter- and intra-molecular C-H⋯O and C-H⋯Br hydrogen bonds.
Figures
References
-
- Failla, S., Finocchinro, P. & Belsky, V. K. (1993). J. Inclusion Phenom. Mol. Recognit. Chem.15, 247–258.
-
- Fonge, H., Chitneni, S. K. & Verbruggen, A. (2007). Bioconjugate Chem.18, 1924–1934. - PubMed
-
- Georghiou, P. E., Zhao, P. L., Ashram, M. & Miller, D. O. (1996). J. Org. Chem.61, 3865–3869. - PubMed
-
- Haynes, D. A., Van de Streek, J., Burley, J. C., Jones, W. & Motherwell, W. D. S. (2006). Acta Cryst. E62, o1170–o1172.
-
- Kano, K., Arimoto, S. & Ishimura, T. (1995). J. Chem. Soc. Perkin Trans. 2, pp. 1661–1666.
LinkOut - more resources
Full Text Sources
Miscellaneous