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. 2008 Feb 15;64(Pt 3):m477.
doi: 10.1107/S160053680800425X.

{N,N-Bis[2-(trimethyl-silylamino)eth-yl]-N'-(trimethyl-silyl)ethane-1,2-diamin-ato(3-)-κN}methyl-zirconium(IV)

Samantha N Macmillan, Joseph M Tanski, Rory Waterman

{N,N-Bis[2-(trimethyl-silylamino)eth-yl]-N'-(trimethyl-silyl)ethane-1,2-diamin-ato(3-)-κN}methyl-zirconium(IV)

Samantha N Macmillan et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, [Zr(CH(3))(C(15)H(39)N(4)Si(3))], is a unique example of a triamido-amine-supported zirconium-methyl complex that crystallized as a monomer with trigonal-bipyramidal geometry at zirconium, featuring a Zr-C bond of 2.2963 (16) Å.

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Figures

Fig. 1.
Fig. 1.
A view of complex I, with displacement ellipsoids shown at the 50% probability level. H atoms except those on C(16)have been omitted for clarity.
See this image and copyright information in PMC

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