Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2008 Feb 6;64(Pt 3):o555.
doi: 10.1107/S1600536808003164.

1H-Indole-3-carbaldehyde azine

Affiliations

1H-Indole-3-carbaldehyde azine

Mohd Razali Rizal et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The molecule of the title compound, C(18)H(14)N(4), lies on a center of inversion such that there is one half-mol-ecule in the asymmetric unit. The N-N single bond adopts a trans configuration and the indole fused-ring system is nearly coplanar with the -CH=N-N=CH- fragment [dihedral angle = 9.8 (2)°]. Adjacent mol-ecules are linked by indole-azine N-H⋯N hydrogen bonds into a layer motif.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
Displacement ellipsoid plot of (I) at the 50% probability level. H atoms are drawn as spheres of arbitrary radiius.
Fig. 2.
Fig. 2.
Layer structure of (I).

References

    1. Alemany, A., Bernabe, M., Fernandez Alvarez, E., Lora-Tamayo, M. & Nieto Lopez, O. (1970). Anal. Quim.66, 681–688.
    1. Barbour, L. J. (2001). J. Supramol. Chem.1, 189–191.
    1. Bruker (2007). APEX2 and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Burke-Laing, M. & Laing, M. (1976). Acta Cryst. B32, 3216–3224.
    1. Lin, C.-J., Hwang, W.-S. & Chiang, M. J. (2001a). J. Organomet. Chem.640, 85–92.