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. 2008 Feb 15;64(Pt 3):o592.
doi: 10.1107/S1600536808004054.

2-[2-(4-Methyl-benzo-yl)-3,3-bis-(methyl-sulfan-yl)prop-2-enyl-idene]malononitrile

Joseph Nirmala, N V Unnikrishnan, C V Asokan, E R Anabha, C Sudarsanakumar

2-[2-(4-Methyl-benzo-yl)-3,3-bis-(methyl-sulfan-yl)prop-2-enyl-idene]malononitrile

Joseph Nirmala et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(16)H(14)N(2)OS(2), is an example of a push-pull butadiene in which the electron-releasing and electron-withdrawing attachments on either end of the butadiene chain enhance the conjugation in the system. The mol-ecules are linked by inter-molecular C-H⋯N inter-actions.

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Figures

Fig. 1.
Fig. 1.
An ORTEPII (Johnson, 1976) view of (I) showing the atom-labeling scheme; displacement ellipsoids are drawn at 50% probability level.
Fig. 2.
Fig. 2.
A view of the unit cell packing of (I) showing intermolecular interactions in the ac plane.
See this image and copyright information in PMC

References

    1. Anabha, E. R. & Asokan, C. V. (2006). Synthesis, 1, 151–155.
    1. Dahne, S. (1978). Science, 199, 1163–1167. - PubMed
    1. Dastidar, P., Guru Row, T. N. & Venkatesan, K. (1993). Acta Cryst. B49, 900–905.
    1. Flack, H. D. (1983). Acta Cryst. A39, 876–881.
    1. Freier, T., Michalik, M. & Peseke, K. (1999). J. Chem. Soc. Perkin Trans. 2, pp. 1265–1271.

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