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. 2008 Mar 29;64(Pt 4):m592.
doi: 10.1107/S160053680800809X.

Bis(2-eth-oxy-6-formyl-phenolato-κO,O)nickel(II)

Affiliations

Bis(2-eth-oxy-6-formyl-phenolato-κO,O)nickel(II)

Zhen-Quan Han. Acta Crystallogr Sect E Struct Rep Online. .

Retraction in

  • Retraction of articles.
    IUCr Editorial Office. IUCr Editorial Office. Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 17;66(Pt 4):e21-2. doi: 10.1107/S1600536809054300. Acta Crystallogr Sect E Struct Rep Online. 2010. PMID: 21580459 Free PMC article.

Abstract

The title compound, [Ni(C(9)H(9)O(3))(2)], was synthesized by the reaction of 3-ethoxy-salicylaldehyde with nickel(II) nitrate in methanol solution. The asymmetric unit onsists of two half-molecules; each Ni atom lies on a centre of symmetry. The Ni(II) ions are coordinated by four O atoms from two deprotonated 3-ethoxy-salicylaldehyde ligands in a slightly distorted square-planar coordination environment.

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Figures

Fig. 1.
Fig. 1.
The molecular structures of the two centrosymmetric independent molecules, showing 30% probability displacement ellipsoids and the atom-numbering scheme. The unlabeled atoms are related by the symmetry operators (-x, -y+1, -z) and (-x, -y, -z) for the molecules containing Ni1 and Ni2 respectively.

References

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