Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2008 Mar 5;64(Pt 4):o661-2.
doi: 10.1107/S1600536808005527.

tert-Butyl 5-(4-methoxy-phen-yl)-1-methyl-2-oxopyrrolidin-3-yl carbonate

tert-Butyl 5-(4-methoxy-phen-yl)-1-methyl-2-oxopyrrolidin-3-yl carbonate

M Fazli Mohammat et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C(17)H(23)NO(5), the pyrrolidinone ring is in an envelope conformation. The tert-butyl carbonate and 4-methoxy-phenyl groups are arranged on the same side of the pyrrolidinone ring. The meth-oxy group is coplanar with the attached benzene ring. The mol-ecules are linked into chains along the b axis via C-H⋯O hydrogen bonds.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound, showing 50% probability displacement ellipsoids and the atomic numbering.
Fig. 2.
Fig. 2.
The crystal packing of the title compound, viewed approximately along the b axis. Hydrogen bonds are shown as dashed lines.

References

    1. Allen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G. & Taylor, R. (1987). J. Chem. Soc. Perkin Trans. 2, pp. S1–S19.
    1. Bruker (2005). APEX2, SAINT and SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Chandrasekhar, S., Jagadeshwar, V. & Prakash, S. J. (2005). Tetrahedron Lett.46, 3127–3129.
    1. Chandrasekhar, S., Saritha, B., Jagadeshwar, V. & Prakash, S. J. (2006). Tetrahedron Asymmetry, 17, 1380–1386.
    1. Cremer, D. & Pople, J. A. (1975). J. Am. Chem. Soc.97, 1354–1358.