4-(9-Anthr-yl)-1-(4-methoxy-phen-yl)spiro-[azetidin-3,9'-xanthen]-2-one
- PMID: 21202385
- PMCID: PMC2961274
- DOI: 10.1107/S1600536808010908
4-(9-Anthr-yl)-1-(4-methoxy-phen-yl)spiro-[azetidin-3,9'-xanthen]-2-one
Abstract
In the title mol-ecule, C(36)H(25)NO(3), the β-lactam ring is essentially planar, with a dihedral angle of 3.3 (2)° between the two separate three-atom N/C/C planes. The β-lactam ring makes dihedral angles of 28.45 (14), 87.4 (1) and 51.8 (1)° with the mean planes of the benzene, xanthene and anthracene ring systems, respectively. In addition to a weak intra-molecular C-H⋯N hydrogen bond, the crystal structure is stabilized by two weak inter-molecular C-H⋯O hydrogen bonds.
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References
-
- Akkurt, M., Karaca, S., Jarrahpour, A. A., Khalili, D. & Büyükgüngör, O. (2006). Acta Cryst. E62, o866–o868.
-
- Akkurt, M., Yalçın, Ş. P., Jarrahpour, A. A., Nazari, M. & Büyükgüngör, O. (2007). Acta Cryst. E63, o3729–o3730.
-
- Allen, F. H., Kennard, O., Watson, D., Brammer, L., Orpen, A. G. & Taylor, R. (1987). J. Chem. Soc. Perkin Trans. 2, pp. S1–19.
-
- Alonso, E., Del Pozo, C. & Gonzalez, J. (2002). Synlett, pp. 69–72.
-
- Alonso, E., Lopez-Ortiz, F., DelPozo, C., Peralta, E., Macas, A. & Gonzalez, J. (2001). J. Org. Chem.66, 6333–6338. - PubMed
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