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. 2008 Jun 25;64(Pt 7):m955.
doi: 10.1107/S1600536808018540.

Tris[2-(propyl-imino-meth-yl)phenolato-κN,O]iron(III)

Tris[2-(propyl-imino-meth-yl)phenolato-κN,O]iron(III)

Lujiang Hao et al. Acta Crystallogr Sect E Struct Rep Online. .

Retraction in

  • Retraction of articles.
    IUCr Editorial Office. IUCr Editorial Office. Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):e10-1. doi: 10.1107/S1600536811037597. Epub 2012 Mar 31. Acta Crystallogr Sect E Struct Rep Online. 2012. PMID: 22589748 Free PMC article.

Abstract

The title compound, [Fe(C(10)H(12)NO)(3)], is isostructural with its Co(III)-containing analogue. The Fe(III) cation is chelated by three Schiff base ligands via three N and three O atoms, and exhibits a slightly distorted octa-hedral geometry. The longest Fe-O and Fe-N bonds lie trans to each other and may be regarded as axial bonds, while the equatorial plane contains two mutually trans O and two trans N atoms.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of (I), drawn with 30% probability displacement ellipsoids for the non-hydrogen atoms.

References

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