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. 2008 Jun 28;64(Pt 7):m963-4.
doi: 10.1107/S1600536808018953.

Dieth-yl[N-(3-meth-oxy-2-oxidobenzyl-idene)-N'-(oxidomethyl-ene)hydrazine-κO,N,O']tin(IV)

Shaukat Shuja, M Nawaz Tahir, Saqib Ali, Nasir Khalid

Dieth-yl[N-(3-meth-oxy-2-oxidobenzyl-idene)-N'-(oxidomethyl-ene)hydrazine-κO,N,O']tin(IV)

Shaukat Shuja et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the mol-ecule of the title compound, [Sn(C(2)H(5))(2)(C(9)H(8)N(2)O(3))], the Sn atom is five-coordinated in a distorted trigonal-bipyramidal configuration by two O and one N atoms of the tridentate Schiff base ligand in the equatorial plane, and by two C atoms of ethyl groups in the axial positions. In the crystal structure, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title molecule, with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.
Fig. 2.
Fig. 2.
A partial packing diagram of (I). Hydrogen bonds are shown as dashed lines.
See this image and copyright information in PMC

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