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. 2008 Jun 19;64(Pt 7):o1290-1.
doi: 10.1107/S1600536808017844.

2-Amino-N-(2-benz-yloxy-3-methoxy-benzyl-idene)aniline

Mohammed H Al-Douh, Shafida A Hamid, Hasnah Osman, Reza Kia, Hoong-Kun Fun

2-Amino-N-(2-benz-yloxy-3-methoxy-benzyl-idene)aniline

Mohammed H Al-Douh et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(21)H(20)N(2)O(2), a Schiff base ligand, contains two independent mol-ecules (A and B) in the asymmetric unit, with similar conformations. In mol-ecule A, the central benzene ring forms dihedral angles of 30.79 (13) and 23.56 (13)°, respectively, with the amino and benzyl benzene rings, while in mol-ecule B these angles are 32.30 (13) and 13.13 (12)°. The mol-ecular structure is stabilized by intra-molecular N-H⋯N and C-H⋯O hydrogen bonds. The crystal structure is stabilized by N-H⋯N hydrogen bonds and N-H⋯π and C-H⋯π inter-actions.

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Figures

Fig. 1.
Fig. 1.
The asymmetric unit of the title compound. Displacement ellipsoids are drawn at the 30% probability level. Intramolecular interactions are shown as dashed lines.
See this image and copyright information in PMC

References

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