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. 2008 Jul 12;64(Pt 8):m1020-1.
doi: 10.1107/S1600536808021004.

Bis(μ-N-benzyl-N-methyl-dithio-carbamato)-1:2κS,S':S';1:2κS:S,S'-bis-[bis-(N-benzyl-N-methyl-dithio-carbamato-κS,S')thallium(III)]

Corrado Rizzoli, Kuppukkannu Ramalingam, Nagarajan Alexander

Bis(μ-N-benzyl-N-methyl-dithio-carbamato)-1:2κS,S':S';1:2κS:S,S'-bis-[bis-(N-benzyl-N-methyl-dithio-carbamato-κS,S')thallium(III)]

Corrado Rizzoli et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The molecule of the dinuclear title compound, [Tl(2)(C(9)H(10)NS(2))(6)], possesses a crystallographically imposed centre of symmetry. Each Tl(III) atom is seven-coordinated by S atoms of four different dithio-carbamate anions in a distorted penta-gonal-bipyramidal coordination geometry. The crystal structure is stabilized by a C-H⋯S hydrogen-bond inter-action linking complex mol-ecules into chains running parallel to the b axis. Intramolecular C-H⋯S hydrogen bonds are also present.

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Figures

Fig. 1.
Fig. 1.
View of the title dinuclear complex molecule with displacement ellipsoids drawn at the 30% probability level. Hydrogen atoms are omitted for clarity [Symmetry code: (i) = 1 - x, -y, -z].
Fig. 2.
Fig. 2.
View of the crystal packing of the title compound. Intermolecular hydrogen bonds are shown as dashed lines. H atoms not involved in hydrogen bonds are omitted for clarity. Colour codes: Tl red, S yellow, N blue, C grey and H white.
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