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. 2008 Jul 19;64(Pt 8):m1039.
doi: 10.1107/S1600536808022022.

Bis{2-bromo-4-chloro-6-[2-(phenyl-sulfon-yl)hydrazonometh-yl]phenolato-κN,O}copper(II)

Juahir Yusnita  1 , Hapipah M Ali, Subramaniam Puvaneswary, Ward T Robinson, Seik Weng Ng
Affiliations

Bis{2-bromo-4-chloro-6-[2-(phenyl-sulfon-yl)hydrazonometh-yl]phenolato-κN,O}copper(II)

Juahir Yusnita et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The Cu atom in the title compound, [Cu(C(13)H(9)BrClN(2)O(3)S)(2)], is chelated by two deprotonated Schiff base ligands in a square-planar coordination geometry; the Cu atom lies on a center of inversion. The -NH- group of one anion forms an intra-molecular hydrogen bond to the phenolate atom of the symmetry-related ion.

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Figures

Fig. 1.
Fig. 1.
Thermal ellipsoid plot (Barbour, 2001) plot of Cu(C13H9BrClN2O3S)2 at the 70% probability level. Hydrogen atoms are drawn as spheres of arbitrary radius. Hydrogen bonds are denoted by dashed lines. The copper atom lies on a center of inversion, and unlabeled atoms are related to their labeled equivalents by 1 – x, 1 – y, 1 – z.
See this image and copyright information in PMC

References

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