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. 2011 Feb 16;133(6):1694-7.
doi: 10.1021/ja1101695. Epub 2011 Jan 20.

Palladium-catalyzed C-H aminations of anilides with N-fluorobenzenesulfonimide

Kai Sun  1 , Yan Li, Tao Xiong, Jingping Zhang, Qian Zhang
Affiliations

Palladium-catalyzed C-H aminations of anilides with N-fluorobenzenesulfonimide

Kai Sun et al. J Am Chem Soc. .

Abstract

The first amide-directed, palladium-catalyzed, intermolecular, highly selective C-H aminations with the non-nitrene-based nitrogen source N-fluorobenzenesulfonimide have been developed. This methodology might provide a new pathway for directed metal-catalyzed aromatic C-H amination.

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