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. 2011 Feb;67(Pt 2):m43-5.
doi: 10.1107/S0108270111000631. Epub 2011 Jan 11.

Tricarbonyl(η5-cyclopentadienyl)(trifluorohydroxyborato)tungsten

Joachim Roll  1 , Heiko Tewes, Eduardo Castillo Soto, Enrique Oñate Rodríguez
Affiliations

Tricarbonyl(η5-cyclopentadienyl)(trifluorohydroxyborato)tungsten

Joachim Roll et al. Acta Crystallogr C. 2011 Feb.

Abstract

The title compound, [W(C(5)H(5))(HOBF(3))(CO)(3)], has a four-legged piano-stool geometry which is typically found for C(5)H(5)W(CO)(3)X complexes. The HOBF(3)(-) anion is the hydrolysis product of BF(4)(-) and is coordinated via oxygen.

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