Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2011 Apr 7;40(13):3112-5.
doi: 10.1039/c0dt01481h. Epub 2011 Feb 15.

Self-assembled molecular squares containing metal-based donor: synthesis and application in the sensing of nitro-aromatics

Vaishali Vajpayee  1 , Hyunuk Kim, Anurag Mishra, Partha Sarathi Mukherjee, Peter J Stang, Min Hyung Lee, Hwan Kyu Kim, Ki-Whan Chi
Affiliations

Self-assembled molecular squares containing metal-based donor: synthesis and application in the sensing of nitro-aromatics

Vaishali Vajpayee et al. Dalton Trans. .

Abstract

Self-assemblies between a linear Pt-based donor and ferrocene- chelated metallic acceptors produced novel heterometallic squares 4 and 5, which show fluorescence quenching upon the addition of nitro-aromatics.

PubMed Disclaimer

Figures

Fig. 1
Fig. 1
31P NMR spectra of the complexes 4 (left) and 5 (right).
Fig. 2
Fig. 2
X-ray crystal structure of 4 (left) and 5 (right). Color codes: yellow = Pd, green = Pt, brown = Fe, orange = P, gray = C. H-atoms are omitted for clarity and pertinent bond distances and angles are given in the text.
Fig. 3
Fig. 3
Emission quenching of 4 upon addition of the various guest molecules (1 × 10−4 M in THF). BA = benzoic acid, 2,4,6-TMP = 2,4,6-trimethylphenol, PG = phloroglucinol, 4-NB = 4-nitrobenzene, 1,3,5-TNB = 1,3,5-trinitrobenzene, PA = picric acid.
Fig.4
Fig.4
Emission quenching of complex 4 by picric acid and Stern-Volmer plot (inset).
Scheme 1
Scheme 1
Self-assembly of the heterometallic squares 4 and 5.
See this image and copyright information in PMC

References

    1. Lehn J-M. Supramolecular Chemistry, concepts and perspectives. VCH; New York: 1995.
    2. Leininger S, Olenyuk B, Stang PJ. Chem Rev. 2000;100:853. - PubMed
    3. Cotton FA, Lin C, Murillo CA. Acc Chem Res. 2001;34:759. - PubMed
    4. Schalley CA, Lutzen A, Albrecht M. Chem-Eur J. 2004;10:1072. - PubMed
    5. Northrop BH, Yang HB, Stang PJ. Chem Commun. 2008:5896. - PMC - PubMed
    1. Lehn JM. Angew Chem, Int Ed Engl. 1990;29:1304.
    2. Yaghi OM, O’Keeffe M, Ockwig NW, Chae HK, Eddaoudi M, Kim J. Nature. 2003;423:705. - PubMed
    3. Bar AK, Chakrabarty R, Mostafa G, Mukherjee PS. Angew Chem Int Ed. 2008;47:8455. - PubMed
    4. Ghosh K, Hu J, White HS, Stang PJ. J Am Chem Soc. 2009;131:6695. - PMC - PubMed
    5. Sawada T, Yoshizawa M, Sato S, Fujita M. Nature Chemistry. 2009;1:53. - PubMed
    1. Stahl J, Mohr W, de Quadras L, Peters TB, Bohling JC, Martin-Alvarez JM, Owen GR, Hampel Gladysz A. J Am Chem Soc. 2007;129:8282. - PubMed
    2. Hamilton TD, Buĉar D-K, MacGillivray LR. Chem Commun. 2007:1603. - PubMed
    3. Ghosh S, Mukherjee PS. Organometallics. 2007;26:3362.
    1. Holliday B, Mirkin CA. Angew Chem, Int Ed. 2001;40:2022. - PubMed
    2. Heo J, Jeon YM, Mirkin CA. J Am Chem Soc. 2007;129:7712. - PubMed
    3. Chi KW, Addicott C, Arif AM, Das N, Stang PJ. J Org Chem. 2003;68:9798–9801. - PubMed
    4. Peinador C, Pía E, Blanco V, García MD, Quintela JM. Org Lett. 2010;12:1380. - PubMed
    5. Sakata Y, Hiraoka S, Shionoya M. Chem Eur J. 2010;16:3318. - PubMed
    1. Fujita M, Umemoto K, Yoshizawa M, Fujita N, Kusukawa T, Biradha K. Chem Commun. 2001:509.
    2. Yang HB, Northrop BH, Zheng YR, Ghosh K, Stang PJ. J Org Chem. 2009;74:7067. - PMC - PubMed
    3. Yang HB, Hawkridge AM, Huang SD, Das N, Bunge SD, Muddiman DC, Stang PJ. J Am Chem Soc. 2007;129:2120. - PubMed

Publication types