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. 2011 Mar 18;13(6):1490-3.
doi: 10.1021/ol200177f. Epub 2011 Feb 18.

Asymmetric synthesis of tertiary and quaternary allyl- and crotylsilanes via the borylation of lithiated carbamates

Varinder K Aggarwal  1 , Michael Binanzer, M Carolina de Ceglie, Maddalena Gallanti, Ben W Glasspoole, Stephanie J F Kendrick, Ravindra P Sonawane, Ana Vázquez-Romero, Matthew P Webster
Affiliations

Asymmetric synthesis of tertiary and quaternary allyl- and crotylsilanes via the borylation of lithiated carbamates

Varinder K Aggarwal et al. Org Lett. .

Abstract

Tertiary allyl- or crotylsilanes have been prepared in high er and dr via the lithiation-borylation reaction of alkyl carbamates with silaboronates. Using a related strategy, quaternary allylsilanes could be accessed in similarly high er.

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