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. 2011 Feb 25;50(9):2171-3.
doi: 10.1002/anie.201007325. Epub 2011 Jan 20.

Nickel-catalyzed amination of aryl sulfamates

Stephen D Ramgren  1 , Amanda L Silberstein, Yang Yang, Neil K Garg
Affiliations

Nickel-catalyzed amination of aryl sulfamates

Stephen D Ramgren et al. Angew Chem Int Ed Engl. .
No abstract available

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Figures

Scheme 1
Scheme 1
Amination of aryl sulfamates and linezolid (4).
Scheme 2
Scheme 2
Synthesis of linezolid (4) using Ni-catalyzed amination. SIPr·HCl=1,3-bis-(2,6-diisopropylphenyl)imidazolinium chloride, [Ni-(cod)2]=bis(1,5-cycloactadiene)nickel(0), NIS=N-iodosuccinimide, TFA=trifluoroacetic acid.
See this image and copyright information in PMC

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