Palladium- and nickel-catalyzed aminations of aryl imidazolylsulfonates and sulfamates
- PMID: 21351758
- DOI: 10.1021/ol200267b
Palladium- and nickel-catalyzed aminations of aryl imidazolylsulfonates and sulfamates
Abstract
A nickel complex derived from dppf, along with NaOt-Bu as the base, allowed for challenging aminations of aryl sulfamates. An improved functional group tolerance is observed in novel palladium-catalyzed aminations of imidazolylsulfonates with rac-BINAP as the ligand.
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