Nitrosamines and water

Abstract

This paper provides an overview of all current issues that are connected to the presence of nitrosamines in water technology. N-nitrosodimethylamine (NDMA) is the most frequently detected member of this family. Nitrosamines became the hottest topic in drinking water science when they were identified as disinfection by-products (DBPs) in chloraminated waters. The danger that they pose to consumer health seems to be much higher than that from chlorinated DBPs. This review summarizes our contemporary knowledge of these compounds in water, their occurrence, and precursors of nitrosamines in drinking and wastewaters, in addition to attempts to remove nitrosamines from water. The paper also reviews our knowledge of the mechanisms of nitrosamine formation in water technology. The current, commonly accepted mechanism of NDMA formation during chloramination of drinking waters assumes that dichloramine reacts with dimethylamine, forms unsymmetrical dimethylhydrazine and further oxidizes to NDMA. The question to answer is which precursors are responsible for delivering the DMA moiety for the reaction since the presence of DMA in water cannot explain the quantities of NDMA that are formed. There are also reports that other oxidants that are commonly used in water technology may generate NDMA. However, the mechanisms of such transformations are unknown. Methods for the removal of nitrosamines from water are described briefly. However, the research that has been undertaken on such methods seems to be at an early stage of development. It is predicted that photolytic methods may have the greatest potential for technological application.