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. 2011 Feb 11;106(6):063003.
doi: 10.1103/PhysRevLett.106.063003. Epub 2011 Feb 11.

Properties of hollow molecules probed by single-photon double ionization

P Lablanquie  1 , F Penent, J Palaudoux, L Andric, P Selles, S Carniato, K Bučar, M Zitnik, M Huttula, J H D Eland, E Shigemasa, K Soejima, Y Hikosaka, I H Suzuki, M Nakano, K Ito
Affiliations

Properties of hollow molecules probed by single-photon double ionization

P Lablanquie et al. Phys Rev Lett. .

Abstract

The formation of hollow molecules (with a completely empty K shell in one constituent atom) through single-photon core double ionization has been demonstrated using a sensitive magnetic bottle experimental technique combined with synchrotron radiation. Detailed properties are presented such as the spectroscopy, formation, and decay dynamics of the N(2)(2+) K(-2) main and satellite states and the strong chemical shifts of double K holes on an oxygen atom in CO, CO2, and O2 molecules.

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