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. 2011 Apr 28;47(16):4805-7.
doi: 10.1039/c1cc10426h. Epub 2011 Mar 16.

Unprecedented ipso aromatic nucleophilic substitution upon oxidative decarboxylation of tris(p-carboxyltetrathiaaryl)methyl (TAM) radicals: a new access to diversely substituted TAM radicals

Christophe Decroos  1 , Thierry Prangé, Daniel Mansuy, Jean-Luc Boucher, Yun Li
Affiliations

Unprecedented ipso aromatic nucleophilic substitution upon oxidative decarboxylation of tris(p-carboxyltetrathiaaryl)methyl (TAM) radicals: a new access to diversely substituted TAM radicals

Christophe Decroos et al. Chem Commun (Camb). .

Abstract

A new reaction of oxidative substitution of aromatic carboxyl groups on stable trityl radical derivatives (TAMs) by various nucleophiles is described; it leads to a wide variety of new persistent and diversely substituted TAM radicals.

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