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. 2011 May 6;76(9):3498-501.
doi: 10.1021/jo101942f. Epub 2011 Mar 23.

Pd-diimine: a highly selective catalyst system for the base-free oxidative Heck reaction

Aditya L Gottumukkala  1 , Johannes F Teichert, Dorus Heijnen, Niek Eisink, Simon van Dijk, Catalina Ferrer, Adri van den Hoogenband, Adriaan J Minnaard
Affiliations

Pd-diimine: a highly selective catalyst system for the base-free oxidative Heck reaction

Aditya L Gottumukkala et al. J Org Chem. .

Abstract

Pd(OAc)(2)/3 is an efficient catalyst system for the base-free oxidative Heck reaction that outperforms the currently available catalysts for the more challenging substrates studied. The catalyst system is highly selective, and works at room temperature with dioxygen as the oxidant.

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