Robustness of quantum dot power-law blinking

Abstract

Photon emission from quantum dots (QDs) and other quantum emitters is characterized by abrupt jumps between an "on" and an "off" state. In contrast to ions and atoms however, the durations of bright and dark periods in colloidal QDs curiously defy a characteristic time scale and are best described by a power-law probability distribution, i.e., ρ(τ) ∝ τ(-α). We controllably couple a single colloidal QD to a single gold nanoparticle and find that power-law blinking is preserved unaltered even as the gold nanoparticle drastically modifies the excitonic decay rate of the QD. This resilience of the power law to change provides evidence that blinking statistics are not swayed by environment-induced variations in kinetics and provides clues toward the mechanism responsible for universal fluorescence intermittency.