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. 2011 Feb 26;67(Pt 3):m386.
doi: 10.1107/S1600536811006866.

Di-tert-butyl-chlorido(N,N-dibenzyl-dithio-carbamato)tin(IV)

Amirah Faizah Abdul Muthalib, Ibrahim Baba, Mohamed Ibrahim Mohamed Tahir, Edward R T Tiekink

Di-tert-butyl-chlorido(N,N-dibenzyl-dithio-carbamato)tin(IV)

Amirah Faizah Abdul Muthalib et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The Sn(IV) atom in the title diorganotin dithio-carbamate, [Sn(C(4)H(9))(2)(C(15)H(14)NS(2))Cl], is penta-coordinated by an asymmetrically coordinating dithio-carbamate ligand, a Cl atom and two C atoms of the Sn-bound tert-butyl groups. The resulting C(2)ClS(2) donor set defines a coordination geometry inter-mediate between square pyramidal and trigonal bipyramidal with a slight tendency towards the former.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of of (I) showing the atom-labelling scheme and displacement ellipsoids at the 50% probability level.
See this image and copyright information in PMC

References

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