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. 2010 Dec 24;67(Pt 1):m117-8.
doi: 10.1107/S1600536810052530.

Dicarbonyl-chlorido(phen-oxy-thio-carbonyl-κC,S)bis-(triphenyl-phosphane-κP)molybdenum(II)

Gene-Hsiang Lee, Hsiao-Fen Wang, Kuang-Hway Yih, Shou-Ling Huang

Dicarbonyl-chlorido(phen-oxy-thio-carbonyl-κC,S)bis-(triphenyl-phosphane-κP)molybdenum(II)

Gene-Hsiang Lee et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title complex, [Mo(C(7)H(5)OS)Cl(C(18)H(15)P)(2)(CO)(2)], the geometry around the metal atom is a capped octa-hedron. The phen-oxy-thio-carbonyl ligand coordinates the Mo(II) atom through the C and S atoms. A one-dimensional structure is formed by π-π inter-molecular inter-actions and a supra-molecular aggregation is determined by inter-molecular C-H⋯O, C-H⋯Cl, C-H⋯π(arene) hydrogen bonds and CO⋯π(arene) inter-actions [O⋯centroid distances = 3.485 (4) and 3.722 (3) Å].

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Figures

Fig. 1.
Fig. 1.
The molecular structure of (I), with atom labels and the 50% probability displacement ellipsoids.
Fig. 2.
Fig. 2.
The packing diagram of (I), showing the π-π interaction and 1-D chain structure.
Fig. 3.
Fig. 3.
The packing diagram of (I), showing the intermolecular C—H···O, C—H···π(arene) hydrogen bonds and CO···π(arene) interactions.
See this image and copyright information in PMC

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