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. 2010 Dec 18;67(Pt 1):m99-m100.
doi: 10.1107/S1600536810051962.

Dichlorido(η-p-cymene)(4-fluoro-aniline-κN)ruthenium(II)

Richard E Sykora  1 , Andrew G Harris, Jason W Clements, Norris W Hoffman
Affiliations

Dichlorido(η-p-cymene)(4-fluoro-aniline-κN)ruthenium(II)

Richard E Sykora et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, [RuCl(2)(C(10)H(14))(C(6)H(6)FN)], a pseudo-octa-hedral d(6) complex, has the expected piano-stool geometry around the Ru(II) atom. The fluoro-aniline ring forms a dihedral angle of 19.3 (2)° with the p-cymene ring. In the crystal, two mol-ecules form an inversion dimer via a pair of N-H⋯Cl hydrogen bonds. Weak inter-molecular C-H⋯Cl inter-actions involving the p-cymene ring consolidate the crystal packing.

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Figures

Fig. 1.
Fig. 1.
A thermal ellipsoid plot (50%) of the title compound showing the labeling scheme.
Fig. 2.
Fig. 2.
31P{1H} NMR Spectrum of the Equilibrium Mixture Prepared by Mixing Equimolar Amounts of (η6-p-cymene)Ru(4—F—C6H4NH2)Cl2 and P(O-2,4-But2-C6H3)3 in CDCl3 at 23 °C.
Fig. 3.
Fig. 3.
19F NMR Spectrum of the Equilibrium Mixture Prepared by Mixing Equimolar Amounts of (η6-p-cymene)Ru(4—F—C6H4NH2)Cl2 and P(O-2,4-But2-C6H3)3 in CDCl3 at 23 °C.
See this image and copyright information in PMC

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