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. 2010 Dec 11;67(Pt 1):o67.
doi: 10.1107/S1600536810050361.

(S)-N-Benzyl-2-methyl-1,2,3,4-tetra-hydro-isoquinoline-3-carboxamide

Tricia Naicker, Thavendran Govender, Hendrik G Kruger, Glenn E M Maguire

(S)-N-Benzyl-2-methyl-1,2,3,4-tetra-hydro-isoquinoline-3-carboxamide

Tricia Naicker et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The structure of the title compound, C(18)H(20)N(2)O, at 173 K has hexa-gonal (P6(1)) symmetry. The N-containing six-membered ring assumes a half-chair conformation. In the crystal, inter-molecular N-H⋯O hydrogen bonding via the amide groups cross-link the mol-ecules along the a axis. The absolute configuration was confirmed by 2D NMR studies.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of compound 1 with the atom numbering scheme. Displacement ellipsoids are drawn at the 50% probability level. Hydrogen atoms have been omitted for clarity.
Fig. 2.
Fig. 2.
Hydrogen bonding interactions between atoms N2—H2···O1.
See this image and copyright information in PMC

References

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