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. 2011 Jan 15;67(Pt 2):m203-4.
doi: 10.1107/S1600536811000870.

Bis(trimethyl-ammonium) tetra-chlorido-diphenyl-stannate(IV)

Tidiane Diop, Libasse Diop, K C Kieran Molloy, Gabrielle Kocioc-Köhn

Bis(trimethyl-ammonium) tetra-chlorido-diphenyl-stannate(IV)

Tidiane Diop et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, [(CH(3))(3)NH](2)[Sn(C(6)H(5))(2)Cl(4)], consists of [(CH(3))(3)NH](+) cations and [SnPh(2)Cl(4)](2-) anions in which the Sn atom, located on a centre of inversion, is bonded to four Cl atoms and two phenyl rings, giving an octa-hedral geometry with the phenyl rings in trans positions. In the crystal, the cations and the anions are connected by N-H⋯Cl hydrogen bonds and C-H⋯Cl inter-actions.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound with the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level [the C-bound H-atoms have been omitted for clarity; symmetry code: (') = -x + 1, -y + 1, -z + 1].
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