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. 2011 Jan 22;67(Pt 2):m252.
doi: 10.1107/S1600536811002510.

6-Cyclo-hexyl-6,7-dihydro-dibenzo[c,f][1,5]aza-bis-mocin-12(5H)-yl(N→Bi) trifluoro-methane-sulfonate

Nianyuan Tan, Xiaowen Zhang

6-Cyclo-hexyl-6,7-dihydro-dibenzo[c,f][1,5]aza-bis-mocin-12(5H)-yl(N→Bi) trifluoro-methane-sulfonate

Nianyuan Tan et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Bi(C(20)H(23)N)(CF(3)SO(3))], the Bi(III) ion shows a distorted pseudo-trigonal-bipyramidal geometry, with two C atoms and a lone electron pair of the Bi atom in equatorial positions and the N and O atoms at the apical positions. The cyclo-hexyl group is disordered over two orientations with site-occupancy factors of 0.600 (14) and 0.400 (14).

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound with atomic numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. All hydrogen atoms are omitted for clarity. The cyclohexyl group was found to be disordered over two positions and modelled with site-occupancy factors, from refinement of 0.600 (14)(Part A) and 0.400 (14)(Part B).
See this image and copyright information in PMC

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